in acetic acid byproducts: C6H5CH2OCOCH3; addn. of mixt. of benzaldehyde and excess acetic acid to zinc dust, stirring ( room temp., 12 h); filtration;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 68, # 1 p. 282 - 284
copper(l) iodide; EtZnBr in neat (no solvent) CuI, Zn were placed in reactor, evacuated for 10 min, filled with Ar, ligand and EtZnBr were added, heated to 38-40°C for 4.5 h, cooled to room temp.; vac. distilled;
参考文献
Eremeev; Danov; Skudin; Sakhipov
Russian Journal of General Chemistry, 2003 , vol. 73, # 4 p. 556 - 559
ethyl iodide, heated with granulated Zn and Zn dust at 80 up to 96°C, is forming ZnEt2 and ZnI2;;
参考文献
McCleary, R. F.; Degering, E. F.
Pr. Indian Acad. Sci., 1934 , vol. 43, p. 127 - 131
Full Text Show Details
Meyer, M.
Chem. News J. Ind. Sci., 1925 , vol. 131, p. 1 - 2
Full Text Show Details
Gmelin Handbook: Zn: SVol., 194, page 600 - 602
trifluoroacetic acid; cobalt(II) dibromide; zinc dibromide in acetonitrile the mixt. in CH3CN was stirred at room temp., then arylbromide was added, stirred at room temp.; GC analysis;
参考文献
Fillon, Hyacinthe; Gosmini, Corinne; Perichon, Jacques
Journal of the American Chemical Society, 2003 , vol. 125, # 13 p. 3867 - 3870
trifluoroacetic acid; cobalt(II) dibromide; zinc dibromide in acetonitrile the mixt. in CH3CN was stirred at room temp., then arylbromide was added, stirred at room temp.; GC analysis;
参考文献
Fillon, Hyacinthe; Gosmini, Corinne; Perichon, Jacques
Journal of the American Chemical Society, 2003 , vol. 125, # 13 p. 3867 - 3870
trifluoroacetic acid; cobalt(II) dibromide; zinc dibromide in acetonitrile the mixt. in CH3CN was stirred at room temp., then arylbromide was added, stirred at room temp.; GC analysis;
参考文献
Fillon, Hyacinthe; Gosmini, Corinne; Perichon, Jacques
Journal of the American Chemical Society, 2003 , vol. 125, # 13 p. 3867 - 3870
