in neat (no solvent) Irradiation (UV/VIS); mixt. of Cl2, SO2 and O2 irradiated (>320 nm) at -78°C; distd. into traps (-90, -120, -196°C); O2 pumped off; distd. intotraps (-70, -110, -196°C) by slow warming to room temp.; peroxid e from -70°C trap purified by trap-to-trap distns.; collected in -50°C trap; detd. by IR, Raman;
参考文献
Romano, Rosana M.; Vedova, Carlos O.Della; Beckers, Helmut; Willner, Helge
Inorganic Chemistry, 2009 , vol. 48, # 5 p. 1906 - 1910
in neat (no solvent) Kinetics; byproducts: S2O3Cl4; Irradiation (UV/VIS); glass vessel; quartz or UV lamp; equilibrium and temps. discussed; further byproduct S2O3Cl4;;
参考文献
Trautz, M.
Zeitschrift fuer Elektrochemie, 1915 , vol. 21, p. 329 - 342
Full Text Show Details
Gmelin Handbook: S: MVol.B3, 130, page 1805 - 1806
Stopperka, K.; Grove, V.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1966 , vol. 347, p. 19 - 23
Full Text Show Details
Gmelin Handbook: S: SVol.3, 2.1.8.9.4.7, page 193 - 193
byproducts: SiF4; other Radiation; photochemical reaction with 253.7 nm radiation, 48 h, in glass vessel;
参考文献
Emeleus, H. J.; Packer, K. J.
Journal of the Chemical Society, 1962 , p. 771 - 775
Full Text View citing articles Show Details
Gmelin Handbook: S: SVol.3, 2.1.8.9.6.2, page 197 - 198
in neat (no solvent) other Radiation; flowing of H2/Ar mixt. through microwave discharge, depositing with Ar/O2 and Ar/SO2 mixts. on CsI window cooled to 17 K; not isolated, detected by IR;
参考文献
Svensson, Thomas; Nelander, Bengt
Chemical Physics, 2003 , vol. 286, # 2-3 p. 347 - 352
