aluminium trichloride in neat (no solvent)
addn. of B-compds. to NMR tube contg. freshly sublimed AlCl3, addn. of C2H5Cl, sealed, warmed form -190°C to room temp., kept for 8 d; not isolated; detected by NMR;
参考文献
Nam, Wonwoo; Onak, Thomas
Inorganic Chemistry, 1987 , vol. 26, p. 1581 - 1586
Doren, J. M. Van; Barlow, S. E.; DePuy, C. H.; Bierbaum, V. M.; Dotan, I.; Ferguson, E. E.
Journal of Physical Chemistry, 1986 , vol. 90, # 12 p. 2772 - 2777
oxygen; chlorine in gas
T=21.9°C; P=700 Torr; Irradiation5-700 Torr partial pressure of O2, dilution by N2; Rate constantProduct distributionMechanism;
参考文献
Shi, Jichun; Wallington, Timothy J.; Kaiser, E. W.
Journal of Physical Chemistry, 1993 , vol. 97, # 23 p. 6184 - 6192
