dipotassium peroxodisulfate; sulfuric acid; copper diacetate; silver nitrate in water T=57°C; 3 h; without cupric acetate, various temperatures and acidities, (NH4)2S2O8 for K2S2O8; Product distributionRate constantMechanism;
参考文献
Journal of Organic Chemistry, , vol. 45, # 23 p. 4752 - 4757
phenanthrene in benzene T=25°C; Irradiationabsolute quenching rate constants obtained by nanosecond flash photolysis technique for a series of photosensitisers; other solvent (CH3CN); t-BuO-radical's yield determination by diphenylhydroxymethyl radical adsorbtion at 540 nm; potential E profiles; Rate constantThermodynamic dataKinetics;
参考文献
Journal of the American Chemical Society, , vol. 103, # 3 p. 640 - 645