lithium aluminium tetrahydride; TiI4 in tetrahydrofuran T=-5°C; 0.5 h; further reagents: TiCl3-LiAlH4, TiCl4-LiAlH4, TiCl3-Mg; various conditions: t (deg C) 66-0; time (min) 60-30;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 13 p. 1771 - 1774
1: monofluoro-trichloromethane With tributylphosphine in dichloromethane
T=0 - 20°C; phosphonium salt formation; 4 h;
2: benzaldehyde in dichloromethane
T=20°C; Wittig reaction; 18 h;
3: With sodium hydroxide; water in dichloromethane
T=20°C; Hydrolysis; 17 h; Title compound not separated from byproducts;
lithium aluminium tetrahydride; TiI4 in tetrahydrofuran
T=-5°C; 0.5 h;
参考文献
Garcia, Mariano; Campo, Carmen del; Llama, Emilio F.; Sinisterra, Jose V.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 13 p. 1771 - 1774
