2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
1,4-dioxane; sodium trifluoroethoxide; p-toluenesulfonyl chloride T=160 - 185°C;
参考文献
Pennsalt Chem.Corp.
Patent: GB814493 , 1956 ;
反应条件
in benzene Irradiation; Product distribution;
参考文献
Slegt, Micha; Minne, Floor; Zuilhof, Han; Overkleeft, Hermen S.; Lodder, Gerrit
European Journal of Organic Chemistry, 2007 , # 32 p. 5353 - 5363
反应条件
1: 2,2,2-trifluoroethanol With sodium t-butanolate in DMF (N,N-dimethyl-formamide) T=0 - 25°C; 1 h; 2: 5-bromo-2-(2,2,2-trifluoroethoxy)benzoic acid With copper(I) bromide in DMF (N,N-dimethyl-formamide) T=100°C; 10 h;
参考文献
Wang, Zhi-Xian; Li, Yuanqiang; Guntoori, Bhaskar Reddy
Patent: US2005/59825 A1, 2005 ;
Location in patent: Page/Page column 4 ;
反应条件
potassium tert-butylate; copper monobromide in tetrahydrofuran; water
参考文献
Fabian, Kai; Enke, Steffen; Tilly, Herbert
Patent: US2003/176721 A1, 2003 ;
反应条件
2,6-dimethylpyridine T=20°C; 3 h; Irradiation;
参考文献
Tetrahedron Letters, , vol. 39, # 52 p. 9755 - 9758
反应条件
2,6-dimethylpyridine T=20°C; 3 h; Irradiation;
参考文献
Tetrahedron Letters, , vol. 39, # 52 p. 9755 - 9758
反应条件
T=25°C; Solvolysis; Kinetics; Concentration;
参考文献
Bentley, T. William; Koo, In Sun
Arkivoc, 2012 , vol. 2012, # 7 p. 25 - 34
反应条件
sulfuric acid in water; acetonitrile T=21°C; 1 h; Irradiationinvestigation of the selectivity of the phenethyl carbenium ion in the photoaddition of a binary aq. sol. of the corresponding alcohol; structural and nucleophilic effects are discussed; Product distributionQuantum yieldRate constant;
参考文献
Anderson, Steven W.; Yates, Keith
Canadian Journal of Chemistry, 1988 , vol. 66, p. 2412 - 2421
反应条件
tetraethylammonium bromide; triethylamine T=135°C; 360 h; Product distributionMechanism;
参考文献
Chemische Berichte, , vol. 117, # 9 p. 2815 - 2824
反应条件
water in acetonitrile T=25°C; Product distribution; Further Variations:Temperatures;
参考文献
Bentley, T. William; Koo, In Sun
Arkivoc, 2012 , vol. 2012, # 7 p. 25 - 34
