2,2,2-三氟乙醇合成路线 （共 1089 条）
反应条件
1: 2,2,2-trifluoroethanol With sodium hydride T=0°C; 2: 1-chloro-4-dichloromethyl-2-methoxy-benzene With silver carbonate in 2,2,2-trifluoroethanol T=0 - 85°C; 1.58333 h; Product distribution / selectivity;
参考文献
Edwards, Brooks; Juo, Rouh-Rong; Sparks, Alison L.
Patent: US2006/79699 A1, 2006 ;
Location in patent: Page/Page column 3 ;
反应条件
2,6-dimethylpyridine in benzene 4 h;
参考文献
Ball, Sheldon S.; Andrews, L.J.; Keefer, R.M.
Journal of Organic Chemistry, 1980 , vol. 45, # 3 p. 546 - 547
反应条件
perchloric acid; sodium perchlorate in acetonitrile T=25°C; Equilibrium constant;
参考文献
Richard, John P.; Jagannadham, Vandannapu; Amyes, Tina L.; Mishima, Masaaki; Tsuno, Yuho
Journal of the American Chemical Society, 1994 , vol. 116, # 15 p. 6706 - 6712
反应条件
caesium carbonate 12 h; UV-irradiation;
参考文献
Journal of the American Chemical Society, , vol. 129, # 51 p. 15919 - 15926
反应条件
caesium carbonate; acetone 24 h; UV-irradiationInert atmosphere;
参考文献
Green Chemistry, , vol. 15, # 10 p. 2704 - 2708
反应条件
1: 4-methoxy-phenol With nonafluoro-n-butanesulfonyl fluoride; caesium carbonate in acetonitrile 0.25 h; 2: 2,2,2-trifluoroethanol; allyl-trimethyl-silane With caesium carbonate; acetone in acetonitrile 24 h; Inert atmosphereUV-irradiation;
参考文献
Raviola, Carlotta; Canevari, Veronica; Protti, Stefano; Albini, Angelo; Fagnoni, Maurizio
Green Chemistry, 2013 , vol. 15, # 10 p. 2704 - 2708
反应条件
T=25°C; Solvolysis; Kinetics; Concentration;
参考文献
Arkivoc, , vol. 2012, # 7 p. 25 - 34
反应条件
in water T=70°C; var. of solvent, ΔH(excit.); KineticsProduct distributionThermodynamic data;
参考文献
Chemische Berichte, , vol. 115, # 10 p. 3402 - 3413
反应条件
P=1.005 - 28.7 Torr; Irradiation; Product distributionKinetics;
参考文献
Canadian Journal of Chemistry, , vol. 61, p. 1481 - 1486
反应条件
disodium hydrogenphosphate; potassium dihydrogenphosphate; starch T=35 - 36°C; 168 h; fermentation with baker's yeast at pH 5.9; Yields of byproduct given;
参考文献
Chemistry Letters, , p. 1815 - 1818
