Goldfarb; Smorgonski
Chemische Berichte, 1936 , vol. 69, p. 1037
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1936 , p. 555
Chem. Zentralbl., 1938 , vol. 109, # I p. 1107
Goldfarb; Smorgonski
Chemische Berichte, 1936 , vol. 69, p. 1037
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1936 , p. 555
Chem. Zentralbl., 1938 , vol. 109, # I p. 1107
in benzene
very slow addn. of t-butylamine in benzene to TiCl4 in benzene cooled to ice-water temp., stirred for 18 h (ice-bath removed); (CH3)3NH3Cl filtered off, removal of solvent, extn. (warm petroleum ether), filtered, volume reduced, dried in vac.; elem. anal.;
参考文献
Nielson, Alastair J.
Inorganica Chimica Acta, 1988 , vol. 154, p. 177 - 182
Reihlen, H.; Hake, A.
Liebigs Annalen der Chemie, 1927 , vol. 452, p. 47 - 67
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Gmelin Handbook: Ti: MVol., 5.13.4, page 371 - 374
in Petroleum ether
dropwise addn. of soln. of TiCl4 in petroleum ether (40-60°C) to soln. of 1-triorganoxysilyl 2-phenylhydrazine (equimolar amts., 0 to -10°C, under dry nitrogen), ppt. filtered in a cold atm. of dry N2; washed, dried under reduced pressure; elem. anal.;
