in neat (no solvent, gas phase)
other Radiation; I atoms obtained by microwave discharge of MeI in a quartz flow tube (pressure: 1E-4 Torr); not isolated, detn. by photoelectron spect.;
参考文献
Wang, Dianxun; Li, Ying; Li, Sheng; Zhao, Hengqi
Chemical Physics Letters, 1994 , vol. 222, p. 167 - 170
in neat (no solvent)
vigorous, explosive reaction with formation of I2 and other gases;;
参考文献
Fireman, E.; Fireman, P.
American Chemical Journal, 1903 , vol. 30, p. 116 - 133
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Gmelin Handbook: P: MVol.C, 230, page 527 - 529
Carlson; Gelhaar
Chemiker-Zeitung, 1908 , vol. 32, p. 604 - 604
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Winkler, C.
Dinglers Polytech. J., 1870 , vol. 198, p. 148 - 148
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Gmelin Handbook: Cl: MVol., 122, page 324 - 326
in neat (no solvent)
0.025 mol MoO3 and 0.025 mol KI are mixed and heated in a silica tube at ca. 575 K in vac. (ca. 1E-3 Torr) for periods ranging from 3 to 6 h; intermediate grinding and reheatings required to ensure completion of the reaction; liberated I2 detd. quant.; Li content detd. by at. absorption spectroscopy; Mo(5+) detected by X-ray photoelectron and ESR spectroscopy; chem. anal. for Mo(5+) content;
参考文献
Ganguli; Ganapathi; Gopalakrishnan; Rao
Journal of Solid State Chemistry, 1988 , vol. 74, # 1 p. 228 - 231
in water
an aq. soln. of peroxophosphorous acid, from O3- or F2O-induced autoxid-ation of aq. H3PO3, leads with KI to liberation of I2;;
参考文献
Bockemueller, W.; Goetz, T.
Liebigs Annalen der Chemie, 1934 , vol. 508, p. 263 - 297
Full Text Show Details
Gmelin Handbook: P: MVol.C, 64, page 136 - 138
Ruff, O.
Ber., 1902 , vol. 35, p. 4453 - 4470
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Perret, A.; Perrot, R.
Bulletin de la Societe Chimique de France, 1934 , vol. 1, p. 1531 - 1548
Full Text Show Details
Gmelin Handbook: S: MVol.B3, 135, page 1815 - 1817
