in neat (no solvent, solid phase)
reactants were ground in an agate mortar or in a "wiggle bug" type stainless steel ball vibrator for several minutes to one hour; extd. with CCl4, detected by IR;
参考文献
Fernandez, J.; Gonzalez, E.; Onnate, J. De; Lopez, R.; Navarro, E.
Journal of Solid State Chemistry, 1993 , vol. 107, p. 314 - 318
in melt
melting of K2Cr2O7 with KI and some KBr; no formation of Br2;;
参考文献
Koninck, L. L. de
Bulletin des Societes Chimiques Belges, 1903 , vol. 17, p. 157 - 165
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Gmelin Handbook: Cr: MVol.B, 251, page 556 - 558
in sulfur dioxide
Electrolysis; electrolyzing soln. of NaI in liquid SO2, pptn. of S on cathode, formation of Na2SO3, liberation of I2 on anode;;
参考文献
Bagster; Steele
Chem. News J. Ind. Sci., 1912 , vol. 105, p. 157 - 157
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Bagster; Steele
Chem. News J. Ind. Sci., 1912 , vol. 105, p. 169 - 169
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Gmelin Handbook: Na: MVol., 137, page 449 - 451
in acetone
pptn. of NaCl and formation of I2 by react. of a soln. of N(PCl2)3 in acetone with NaI;;
参考文献
Gmelin Handbook: P: MVol.C, 236, page 539 - 542
Full Text Show Details
Sharpe, A. G.
Paddock, N. L., Searle, H. T. in: Emeleus, H. J., Sharpe, A. G., Advances in inorganic Chemistry and Radiochemistry, Bd. 1, New York 1959, S. 347/83
in perchloric acid
Kinetics; N2-atmosphere; 25.+-.0.1°C, I=0.2 M (NaClO4), excess NaI, 1.10E-5to 5.40E-3 M HClO4; not isolated, reaction followed by UV/VIS spectroscopy;
参考文献
Dozsa, L.; Szilassy, I.; Beck, M. T.
Inorganica Chimica Acta, 1976 , vol. 17, p. 147 - 153
Baubigny, H.; Rivals, P.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1903 , vol. 137, p. 651 - 651
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Gmelin Handbook: I: MVol.2, 47, page 352 - 354
in perchloric acid
Kinetics; N2-atmosphere; 25.+-.0.1°C, I=0.2 M (NaClO4), excess I(1-), 1.10E-5 to 5.40E-3 M HClO4; not isolated, reaction followed by UV/VIS spectroscopy;
参考文献
Dozsa, L.; Szilassy, I.; Beck, M. T.
Inorganica Chimica Acta, 1976 , vol. 17, p. 147 - 153
Longi, A.; Bonavia, L.
Gazzetta Chimica Italiana, 1898 , vol. 28, # I p. 333 - 333
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Gmelin Handbook: I: MVol.2, 153, page 585 - 587
