2-甲基-1,4-戊二烯合成路线 （共 28 条）
反应条件
pumice stone; zirconium oxide
T=300 - 310°C;
参考文献
Nasarow; Mawrow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959 , p. 472,482; engl. Ausg. S. 446, 454
反应条件
1: 74 percent / lithium aluminum hydride
2: triethylamine / CH2Cl2 / 0.5 h / Ambient temperature
3: 48 percent / LiBr / acetone / 9 h / Heating
4: tri-n-butyltin hydride/cyclohexane / various solvent(s) / 0.5 h / 30.9 - 126.9 °C / Irradiation
View Scheme
参考文献
Walton, John C.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 231 - 236
反应条件
1: 48 percent / LiBr / acetone / 9 h / Heating
2: tri-n-butyltin hydride/cyclohexane / various solvent(s) / 0.5 h / 30.9 - 126.9 °C / Irradiation
View Scheme
参考文献
Walton, John C.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 231 - 236
反应条件
(i) Ni(CO)4, benzene, (ii) /BRN= 1361370/, DMF; Multistep reaction;
参考文献
Corey,E.J.; Semmelhack,M.F.
Journal of the American Chemical Society, 1967 , vol. 89, p. 2755 - 2757
反应条件
aluminium
T=310 - 330°C; 0.5 h; Yield given. Yields of byproduct given;
参考文献
Infarnet, Yves; Accary, Armand; Huet, Jean
Bulletin de la Societe Chimique de France, 1980 , vol. 2, # 5-6 p. 261 - 266
反应条件
1: palladium/calcium carbonate / Hydrogenation
2: aluminium phosphate / 300 - 310 °C
View Scheme
参考文献
Nasarow; Mawrow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959 , p. 472,482; engl. Ausg. S. 446, 454
参考文献
Normant
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1954 , vol. 239, p. 1811
反应条件
(i) aq. H2O2, (ii) (thermolysis); Multistep reaction;
参考文献
Ferles,M.; Beran,J.
Collection of Czechoslovak Chemical Communications, 1967 , vol. 32, p. 2998 - 3003
反应条件
in gas
T=330 - 380°C; P=53 - 210 Torr; in the presence of propene; Kinetics;
参考文献
Chuchani, Gabriel; Martin, Ignacio; Alonso, Miguel E.
Journal of Physical Chemistry, 1981 , vol. 85, # 9 p. 1241 - 1243
参考文献
Lewina et al.
Zhurnal Obshchei Khimii, 1951 , vol. 21, p. 233,235,236; engl.Ausg.S.251,253,254
Show Details
Nasarow; Mawrow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959 , p. 472,482; engl. Ausg. S. 446, 454
