hydrogen in neat (no solvent) byproducts: liq. Si compd.; SiCl4 vapors and H2 (in ratio 1:2 mixed) are reacting with Zn (granulated), heated at 350 up to 400°C;;
参考文献
Journal of the American Chemical Society, , vol. 67, p. 1545 - 1548
in neat (no solvent) on passing of dry Cl2 over ZnO at 600 - 700°C in SiO2 tube;; distn. (two times) in vacuum, distn. in dry N2 and quick cooling down; compd. is free from oxide and HCl;;
in neat (no solvent) byproducts: CH3COOH; on passing of dry HCl gas over dry Zn acetate and heating of mixture under heating, little by little liquefaction; ZnCl2 in CH3COOH is obtained (Zn(CH3CO2)2 + HCl = Zn(1+)*2Cl(1-)*CH3COOH);; not isolated;;
参考文献
Journal of the American Chemical Society, , vol. 61, p. 2164 - 2167
