in solid Kinetics; byproducts: CO2, O2; mixt. of Na2CO3 and AgCl in molar ratio 1:3 or 1:2 or 1:1 or 2:1 or 3:1 was ground in mortar with 3-4 drops of H2O; dried at 200°C for 10min; heated at 350-440°C for 5 min; identified by X-ray diffraction;
参考文献
Russian Journal of General Chemistry, , vol. 79, # 10 p. 2081 - 2086
in water aq. soln. of NiCl2*6H2O mixed with aq. soln. of NaBH4, ppt. dried at 423K, reduced with H2 at 873 K for 1 h; washed with H2O; elem. anal.;
参考文献
Journal of Magnetism and Magnetic Materials, , vol. 320, # 3-4 p. 182 - 189
→
反应条件
in neat (no solvent) Kinetics; mixt. of NaClO4 and Fe (molar ratio = 1:1) heated to 730°C in corundum crucibles under atm. pressure at a heating rate of 10 K/min; elem. anal.;
参考文献
Russian Journal of Inorganic Chemistry, , vol. 49, # 8 p. 1240 - 1246
in ethanol byproducts: COD; 1 equiv. of NaBH4, 2 equiv. of phosphine per complex, room temp., few min, gas evolution; evapn., extn. (benzene), recrystn. (benzene/hexane);
