in neat (no solvent) simultaneous reaction of starting material;;
参考文献
Vansheidt, A. A.; Tolstopyatov, V. M.
Zh. russk. fiz.-khim. Obshch., 1920 , vol. 52, p. 270 - 284
C. III, 1923 , p. 724
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Gmelin Handbook: P: MVol.C, 200, page 458 - 460
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反应条件
in neat (no solvent) react. in a sealed tube at 160 °C under discoloration;;
参考文献
Michaelis, A.
Journal fuer Praktische Chemie (Leipzig), 1871 , vol. 4, p. 449 - 457
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Gmelin Handbook: Cu: MVol.B1, 43, page 89 - 91
in neat (no solvent) byproducts: NOCl, NO2Cl, NO; passing dry N2O4 over the surface of freshly distd. PCl3 cooled at -10 °C; absortion under formation of a dark red liq.; expelling NO, N2O3, NOCl, NO2Cl and pptn. of P2O6NCl2; liquid phase contg. POCl3, P2O3Cl4 and a small amount of P4O4Cl10;; isolation of liquid products by fractionation; yield of P2O3Cl4 17 percent and of P4O4Cl10 5 percent;;
Chemische Fabrik von Heyden A.-G.
Patent: DE415312 , 1925 ;
C. II, 1925 , p. 1301
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Gmelin Handbook: S: MVol.B3, 122, page 1791 - 1793
in carbon disulfide hydrolysis of a diluted soln. of PCl3 in CS2; use of Na2CO3*H2O to generate of H2O for hydrolysis; formation of H3PO3, H4P2O5 and POCl3, P4O as by-products;;
参考文献
Boubeau, J.; Schulz, P.
Z. anorg. allg. Chem., 1958 , vol. 294, p. 224 - 232
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Gmelin Handbook: P: MVol.C, 183, page 421 - 424
in carbon disulfide hydrolysis of a diluted soln. of PCl3 in CS2; use of ice at -60 °C to generate of H2O for hydrolysis; formation of H3PO3, H4P2O5 and POCl3, P4O as by-products;;
参考文献
Boubeau, J.; Schulz, P.
Z. anorg. allg. Chem., 1958 , vol. 294, p. 224 - 232
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Gmelin Handbook: P: MVol.C, 183, page 421 - 424
