in neat (no solvent)
in some serially standing chambers Cl2 and H2S react first to HCl and S, then to HCl and S2Cl2; react. is promoted in soln. of H2S and Cl2 in S2Cl2;; poor amounts of Cl2 is washed out in towers filled with charcoal; formed HCl is very pure;;
in neat (no solvent)
storage of SO2Cl2 satd. by H2S in cooling mixture;; increasing temp., increases yield of S2Cl2;;
参考文献
Besson, A.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1896 , vol. 122, p. 467 - 469
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Gmelin Handbook: S: MVol.B3, 106, page 1761 - 1762
Irradiation (UV/VIS); generation of H atoms by photolysis (excimer laser, 80 mJ, 248 nm) of H2S in H2S/ClCN mixt. (1/1, 80-100 mTorr); laser induced fluorescence;
参考文献
Juan, J. de; Callister, S.; Reisler, H.; Segal, G. A.; Wittig, C.
Journal of Chemical Physics, 1988 , vol. 89, p. 1977 - 1985
glass in neat (no solvent)
byproducts: H2SiF6, H2SiO3; red heat;;
参考文献
Moissan, H.; Lebeau, S.
Ann. Chim. Phys., 1902 , vol. 26, p. 145 - 178
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Moissan, H.; Lebeau, S.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1900 , vol. 130, p. 865 - 871
