in neat (no solvent) diln. of HClO4 with D2O; concg. soln.; repeat procedure sometime;; soln. of DClO4 in D2O obtained;;
参考文献
Waggener, W. C.
Journal of Physical Chemistry, 1958 , vol. 62, p. 382 - 382
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Gmelin Handbook: Cl: SVol.B2, 50, page 423 - 425
in further solvent(s) further solvent=benzoylchloride; dropwise addn. of D2O to benzoyl chloride, passing gases through ice cooled tube, absorption in pure H2O, rinsing with air;;
ruthenium trichloride; triethylamine in water-d2 Kinetics; byproducts: DH, H2; Irradiation (UV/VIS); photolysis of D2O/triethylamine in presence of colloidal Ru, formed from added RuCl3 and p-terphenyl;; ratio D2:DH:H2 = 51:38:11;;
参考文献
Journal of Physical Chemistry, , vol. 95, # 15 p. 5802 - 5808