in solid Kinetics; byproducts: CO2, Br2, HBr; various molar ratios of Cu(II) malonate and bromide; 383-433 K; further by-product is an undefined, presumably polymer, compound with a gross composition C1.5OH; mass spectroscopy;;
参考文献
Carr, N. J.; Galwey, A. K.; Mohamed, M. A.
Thermochimica Acta, 1986 , vol. 102, p. 323 - 334
in ethanol Kinetics; reaction of alcoholic soln. of iodine with CuBr2 at 60°C; X-ray diffraction;
参考文献
Batsanov, S. S.; Lazareva, E. V.; Kopaneva, L. I.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1979 , vol. 24, p. 1253 - 1254
Zhurnal Neorganicheskoi Khimii, 1979 , vol. 24, p. 2258 - 2261
in ethylene glycol dimethyl ether Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : ZnI2 : CuBr2 = 8 : 1 : 3; irradn. (254 nm) for 8 h gave deposition of Zn and Cu; examn. of the Zn-Cu powder by ESCA measurement showed that more than 60percent of the sample consisted of a Zn-Cu alloy and that the balance of the particles were Zn and Cu metals;
参考文献
Journal of Organometallic Chemistry, , vol. 464, # 1 p. 11 - 22
NaBH4; O2 KI added to Cu-salt with stirring, Ar bubbled for 15 min, NaBH4 added dropwise, stirred for 2.5-3 h, allowed to stand for 6-12 h; decanted, washed with H2O, EtOH, dried in air at 40-60°C;
in ethanol Kinetics; reaction of alcoholic soln. of iodine with CuBr2 at 60°C; X-ray diffraction;
参考文献
Batsanov, S. S.; Lazareva, E. V.; Kopaneva, L. I.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1979 , vol. 24, p. 1253 - 1254
Zhurnal Neorganicheskoi Khimii, 1979 , vol. 24, p. 2258 - 2261
in ethanol mixing an ethanolic soln. of copper bromide with ethanolic soln. of terpyridine (stoichiometric amount), green ppt.; ppt. washing with ether, recrystallization from water/ethanol, elem. anal.;
参考文献
Arriortua, M. I.; Mesa, J. L.; Rojo, T.; Debaerdemaeker, T.; Beltran-Porter, D.; et al.
Inorganic Chemistry, 1988 , vol. 27, p. 2976 - 2981
