反应条件
in carbon disulfide byproducts: S7, S8, S9; complex and CS2 stirred for 10 min at 25°C with exclusion of moisture, SO2Cl2 soln. rapidly added with stirring, reacted for 30 min; further by-products: S12, S14, S15, S16, S19, S25, S30; filtered, concd. at 70°C, dried over MgSO4, cooled to -78°C, pptd. for 7-10 d, rapidly filtered, extd. (CS2 at 25°C for 15min) with crushing, crude product washed with CS2, then with CHCl3, dried in air, recrystd. (CS2);
参考文献
Steudel, Ralf; Strauss, Reinhard
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 1775 - 1778
