in neat (no solvent) High Pressure; heating at 220-360 °C for 3 h in a rotating autoclave (1.5 l, pressure formed by react: 100 atm); apparatus and handling described;; condensation; fractionation;;
in acetonitrile byproducts: HCl, SiF4; gently refluxing KHF2 suspension; addn. of SO2Cl2 soln. with stirring during 1h; refluxing, 1h; condensing into trap at liq. nitrogen temp.; distn., -100°C; distn., -50°C; separation of SO2ClF; addn. of HI to distillate; passing through KMnO4 soln.; drying over P2O5; storage in a glass globe; elem. anal.;
参考文献
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, , vol. 20, p. 777 - 779
Peratoner; Condorelli
Gazzetta Chimica Italiana, 1898 , vol. 28 I, p. 211
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Bocchi
Gazzetta Chimica Italiana, 1896 , vol. 26 II, p. 405
