in neat (no solvent) Irradiation (UV/VIS); mixt. of Cl2, SO2 and O2 irradiated (>320 nm) at -78°C; distd. into traps (-90, -120, -196°C); O2 pumped off; distd. intotraps (-70, -110, -196°C) by slow warming to room temp.; peroxid e from -70°C trap purified by trap-to-trap distns.; collected in -50°C trap; detd. by IR, Raman;
in neat (no solvent) byproducts: SO2Cl2; heating on a water bath with a reflux condenser; formation of SO2, Cl2, POCl3, small amount of SOCl2 and S2O5Cl2 and traces of SO2Cl2;;
in neat (no solvent) Kinetics; byproducts: S2O3Cl4; Irradiation (UV/VIS); glass vessel; quartz or UV lamp; equilibrium and temps. discussed; further byproduct S2O3Cl4;;
参考文献
Zeitschrift fuer Elektrochemie, , vol. 21, p. 329 - 342
