phosphorus pentachloride in neat (no solvent)
1.) 110-120 deg C, 1 h, 2.) room temp., 2.5 h then 90 deg C, 3 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mahajan; Araujo
Canadian Journal of Chemistry, 1987 , vol. 65, # 1 p. 224 - 225
1: acrylic acid With sodium hypophosphite; sulfuric acid; dihydrogen peroxide in water
T=75 - 90°C; 1 h;
2: ethene With dihydrogen peroxide in water
T=80 - 105°C; P=1875.19 - 2250.23 Torr; 4 h;
3: acrylic acid With dihydrogen peroxide in water
T=75 - 90°C; 1 h; Product distribution / selectivity;
参考文献
Clariant International Ltd
Patent: US2007/210288 A1, 2007 ;
Location in patent: Page/Page column 12 ;
