2-甲基-1-丁烯-3-酮合成路线 （共 116 条）
反应条件
1: hydroxylamine hydrochloride; sodium carbonate / methanol / 1 h / 65 °C / |Inert atmosphere 2: triethylamine / dichloromethane / 0 - 20 °C / |Inert atmosphere 3: dipotassium peroxodisulfate; (pentamethylcyclopentadienyl)*Rh(OAc)2 / 80 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 136, # 7 p. 2735 - 2738
参考文献
Bayer and Co.
Patent: DE242612 ;
反应条件
ozone in polyethylene T=-75°C; 3.5 h;
参考文献
Griesbaum, Karl; Greunig, Hans-Joachim; Volpp, Willi; Jung, In-Chan
Chemische Berichte, 1991 , vol. 124, # 4 p. 947 - 956
反应条件
ozone in dichloromethane-d2 T=-78°C; Title compound not separated from byproducts;
参考文献
Chemische Berichte, , vol. 124, # 4 p. 947 - 956
反应条件
ozone in polyethylene T=-75°C; 4 h; Further byproducts given;
参考文献
Chemische Berichte, , vol. 124, # 4 p. 947 - 956
反应条件
T=55°C; Title compound not separated from byproducts;
参考文献
Peretokin, A. V.; Shutalev, A. D.; Chupin, V. V.; Mergenova, A. M.; Ignatova, L. A.; et al.
Journal of Organic Chemistry USSR (English Translation), 1985 , vol. 21, # 5 p. 912 - 918
Zhurnal Organicheskoi Khimii, 1985 , vol. 21, # 5 p. 1004 - 1011
反应条件
water; [Rh(NCMe)2(cod)][BF4] in tetrahydrofuran T=60°C; 5 h;
参考文献
Oi, Shuichi; Moro, Mitsutoshi; Ito, Hisanori; Honma, Yoshio; Miyano, Sotaro; Inoue, Yoshio
Tetrahedron, 2002 , vol. 58, # 1 p. 91 - 97
反应条件
potassium tetrachloroplatinate(II); potassium hydroxide in 1,4-dioxane; water 2 h; HeatingInert atmosphere;
参考文献
Watanabe, Eiichi; Kaiho, Atsushi; Kusama, Hiroyuki; Iwasawa, Nobuharu
Journal of the American Chemical Society, 2013 , vol. 135, # 32 p. 11744 - 11747
反应条件
hydrogenchloride; TiCl3; sodium nitrite 1.) 0-5 degC, 2.) Acetone, 30 min, 40 degC;
参考文献
Citterio, Attilio; Vismara, Elena
Synthesis, 1980 , # 4 p. 291 - 292
反应条件
aluminium trichloride T=10 - 20°C;
参考文献
Colonge; Pichat
Bulletin de la Societe Chimique de France, 1949 , p. 177,183
