[MoCl5] in tetrahydrofuran; diethyl ether T=-70°C; effect of use of var. solvents; effect of use of var. velocity of allowance; effect of use of Ph-CO-Me; Product distribution;
(molybdenum pentachloride)2 multistep reaction, on the carbonyl-olefinating μ-methylene complex from Mo2Cl10 and four equivalents of Methyllithium; other aldehydes, ketones, 6-Oxo-6-phenylhexanal, azomethines; Product distributionMechanism;
complex from (4R,5R)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane and tris(isopropoxy)chlorotitane in tetrahydrofuran T=-50°C; Yield given. Yields of byproduct given;
参考文献
Seebach, Dieter; Beck, Albert K.; Imwinkelried, Rene; Roggo, Silvio; Wonnacott, Anne
Helvetica Chimica Acta, 1987 , vol. 70, p. 954 - 974
