tributylbenzylphosphonium chloride in diethylene glycol dimethyl ether T=110°C; 24 h; investigation of the regioselective addition reaction of active ester S-phenyl thioacetate with 2-phenoxymethyloxirane was catalyzed by insoluble polystyrene-bound quternary phosphonium or ammonium salts; Product distribution;
T=750°C; P=0.001 - 0.1 Torr; Further byproducts given. Title compound not separated from byproducts;
参考文献
Aitken, R. Alan; Armstrong, Jill M.; Drysdale, Martin J.; Ross, Fiona C.; Ryan, Bruce M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1999 , # 5 p. 593 - 604
in water T=15 - 45°C; ionic strength 0.2 M (KCl), ΔH(excit.), ΔS(excit.), structure-reactivity correlations in the aminolysis; Rate constantThermodynamic dataMechanism;
参考文献
Castro, Enrique A.; Ureta, Carmen
Journal of Organic Chemistry, 1989 , vol. 54, # 9 p. 2153 - 2159
in water T=15 - 45°C; ionic strength 0.2 M and 0.6 M (KCl), ΔH(excit.), ΔS(excit.), structure-reactivity correlations in the aminolysis; Rate constantThermodynamic dataMechanism;
参考文献
Castro, Enrique A.; Ureta, Carmen
Journal of Organic Chemistry, 1989 , vol. 54, # 9 p. 2153 - 2159
