1,2,4,5-四氯苯合成路线 （共 206 条）
反应条件
carbon dioxide; tetrabutylammomium bromide in N,N-dimethyl-formamide T=-5 - 0°C; Dehalogenation; Electrochemical reaction; Further byproducts given;
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 65, # 6 p. 862 - 880
反应条件
1: 66.0 percent Spectr. / NiCl2 hexahydrate; 2,2'-bipyridyl; Zn / H2O; dimethylformamide / 6 h / 80 °C 2: 9.7 percent Spectr. / NiCl2 hexahydrate; 2,2'-bipyridyl; Zn / H2O; dimethylformamide / 6 h / 80 °C View Scheme
参考文献
Vcelak, Jaroslav; Friesova, Anna; Rericha, Roman; Hetflejs, Jiri
Collection of Czechoslovak Chemical Communications, 1994 , vol. 59, # 6 p. 1368 - 1383
参考文献
Silberrad
Journal of the Chemical Society, 1922 , vol. 121, p. 1019
反应条件
disulfur dichloride; aluminium trichloride; thionyl chloride; sulfuryl dichloride T=40 - 80°C;
参考文献
Silberrad
Journal of the Chemical Society, 1922 , vol. 121, p. 1019
反应条件
potassium tert-butylate in N,N,N',N',N'',N''-hexamethylphosphoric triamide 0.00277778 h; Ambient temperatureother reaction times; other solvent: DMF; Product distributionMechanism;
参考文献
Journal of Organic Chemistry, , vol. 45, # 23 p. 4660 - 4666
参考文献
Silberrad
Journal of the Chemical Society, 1922 , vol. 121, p. 1019
反应条件
tetrabutylammomium bromide in N,N-dimethyl-formamide T=-5 - 0°C; Dehalogenation; Carboxylation; Electrochemical reaction; Further byproducts given;
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 65, # 6 p. 862 - 880
反应条件
potassium fluoride in various solvent(s) T=300°C; 8 h; var. times, var. temperatures, other solvents, other metal fluoride, in presence of FeCl3; Product distribution;
参考文献
Kimura, Yoshikazu; Suzuki, Hiroshi
Journal of Fluorine Chemistry, 1992 , vol. 59, # 2 p. 289 - 291
反应条件
1: methanol. NaOH / 160 °C 2: glacial acetic acid; aqueous HNO3 View Scheme
参考文献
Harrison; Peters; Rowe
Journal of the Chemical Society, 1943 , p. 235
反应条件
sodium hydroxide T=275°C;
参考文献
Givaudan Corp.
Patent: US2509245 , 1947 ;
