in neat (no solvent)
ratio (HSO3Cl/PCl5) 1:1; decompn. of S2O5Cl2;;
参考文献
Michaelis, A.
Jena. Z. Med. Naturwiss., 1873 , vol. 7, p. 110 - 117
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Michaelis, A.
Jena. Z. Med. Naturwiss., 1870 , vol. 6, p. 235 - 238
in neat (no solvent)
mixing powdered KClO3 with PCl5; liquefaction of the mass under evolution of heat; at first formation of a gas with detonation, then evolution of Cl2; formation of pure KCl as residue;;
参考文献
Baudrimont, E.
C. r. Acad. Sci. (Paris), 1860 , vol. 51, p. 823 - 825
in neat (no solvent)
ratio (SO3/PCl5) 1:1; decompn. of S2O5Cl2;;
参考文献
Michaelis, A.
Jena. Z. Med. Naturwiss., 1873 , vol. 7, p. 110 - 117
Full Text Show Details
Michaelis, A.
Jena. Z. Med. Naturwiss., 1870 , vol. 6, p. 235 - 238
in neat (no solvent)
distilling NO2 into an U-tube containing PCl5 at 24 °C; vigorous reaction; evolution of Cl2; collecting NOCl with receivers;; NOCl is impured with Cl2; fivefold distillation yield pure NOCl;;
参考文献
Mueller, R.
Liebigs Annalen der Chemie, 1862 , vol. 122, p. 11
