bis(acetylacetonato)(trimethylphosphate)dioxouranium in water T=25°C; reactions of β-diketones under var. conditions; ΔH(excit), ΔS(excit); Rate constantEquilibrium constantMechanism;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 62, # 9 p. 2802 - 2806
1: tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium in benzene T=20°C; 2: With sulfuric acid in benzene 3: diazomethane; (2,4-dinitro-phenyl)-hydrazine Further stages;
参考文献
Russian Journal of General Chemistry, , vol. 79, # 8 p. 1663 - 1670