反式-1,2-二苯乙烯氧化物合成路线 （共 213 条）
反应条件
4,4'-di-tert-butylbiphenyl; lithium in tetrahydrofuran
T=-80 - -50°C; 2.75 h;
参考文献
Yus, Miguel; MacIa, Beatriz; Gomez, Cecilia; Soler, Tatiana; Falvello, Larry R.; Fanwick, Phillip E.
Tetrahedron, 2005 , vol. 61, # 15 p. 3865 - 3871
反应条件
4,4'-di-tert-butylbiphenyl; lithium in tetrahydrofuran
T=-80 - -50°C; 2.75 h;
参考文献
Yus, Miguel; MacIa, Beatriz; Gomez, Cecilia; Soler, Tatiana; Falvello, Larry R.; Fanwick, Phillip E.
Tetrahedron, 2005 , vol. 61, # 15 p. 3865 - 3871
反应条件
4,4'-di-tert-butylbiphenyl; lithium in tetrahydrofuran
T=-80 - -50°C; 2.75 h;
参考文献
Yus, Miguel; MacIa, Beatriz; Gomez, Cecilia; Soler, Tatiana; Falvello, Larry R.; Fanwick, Phillip E.
Tetrahedron, 2005 , vol. 61, # 15 p. 3865 - 3871
反应条件
4,4'-di-tert-butylbiphenyl; lithium in tetrahydrofuran
T=-80 - -50°C; 2.75 h; Title compound not separated from byproducts;
参考文献
Yus, Miguel; MacIa, Beatriz; Gomez, Cecilia; Soler, Tatiana; Falvello, Larry R.; Fanwick, Phillip E.
Tetrahedron, 2005 , vol. 61, # 15 p. 3865 - 3871
反应条件
4,4'-di-tert-butylbiphenyl; lithium in tetrahydrofuran
T=-80 - -50°C; 2.75 h; Title compound not separated from byproducts;
参考文献
Yus, Miguel; MacIa, Beatriz; Gomez, Cecilia; Soler, Tatiana; Falvello, Larry R.; Fanwick, Phillip E.
Tetrahedron, 2005 , vol. 61, # 15 p. 3865 - 3871
反应条件
sodium amide
1.) THF, reflux, 3 h; 2.) THF, r.t., 4 d; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Stamm, Helmut; Lin, Pen-Yuan; Sommer, Andreas; Woderer, Anton
Tetrahedron, 1989 , vol. 45, # 9 p. 2571 - 2578
反应条件
n-butyllithium
1.) hexane, THF, -60 deg C; 2.) THF, hexane, r.t., 5 d; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Stamm, Helmut; Lin, Pen-Yuan; Sommer, Andreas; Woderer, Anton
Tetrahedron, 1989 , vol. 45, # 9 p. 2571 - 2578
反应条件
diethylamino-sulfur trifluoride
T=55 - 60°C;
参考文献
Hudlicky, Milos
Journal of Fluorine Chemistry, 1987 , vol. 36, p. 373 - 384
反应条件
mesoporous aluminosilicate catalyst, Si/Al ratio = 14:1 in chloroform
T=20 - 55°C;
参考文献
Robinson, Mathew W. C.; Davies, A. Matthew; Buckle, Richard; Mabbett, Ian; Taylor, Stuart H.; Graham, Andrew E.
Organic and Biomolecular Chemistry, 2009 , vol. 7, # 12 p. 2559 - 2564
反应条件
1: diethyl ether
2: POCl3; PCl5 / 170 °C
3: ethanolic KOH / 180 °C
View Scheme
参考文献
Kayser
Annales de Chimie (Cachan, France), 1936 , vol. <11> 6, p. 145,176
