in N,N-dimethyl-formamide byproducts: ZnBr2; N2; slight excess of Zn powder added to olefin soln.; mild exotherm reactn. after short induction period; unsepd. prod. mixt. in ratio mono/bis = 67/33; removal of excess Zn by filtrn.;
参考文献
Burton, Donald J.; Hansen, Steven W.
Journal of the American Chemical Society, 1986 , vol. 108, # 14 p. 4229 - 4230
cobalt(II) dibromide; zinc dibromide in acetonitrile the mixt. in CH3CN was stirred at room temp., then thienylbromide was added, stirred at room temp.; GC analysis;
参考文献
Journal of the American Chemical Society, , vol. 125, # 13 p. 3867 - 3870
EtMgI; copper(l) iodide in diethyl ether Zn, ligand, EtMgI and CuI were added to reactor with Et2O, heated at 35°C for 48 h with stirring; decanted, washed with Et2O;
参考文献
Eremeev; Danov; Skudin; Sakhipov
Russian Journal of General Chemistry, 2003 , vol. 73, # 4 p. 556 - 559
