potassium hydroxide in water T=78°C; 7 h; other var. monosaccharines, effects of hydroxyl ion and monosaccharide concentration, effects of inorganic cations and anions, effects of temperature; Product distributionMechanism;
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 105, # 6 p. 176 - 183
potassium hydroxide in water T=78°C; 0.333333 h; isomerization equilibrium; degradation to acids; varying time, OH(1-) concentration 0.001 M to O.1 M; also in presence of Ca(2+) up to 0.06 M; Rate constantProduct distributionMechanism;
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 106, # 2 p. 35 - 43
Fe2(S04)3 in sulfuric acid T=100°C; effect of the temp., the time and the concentration of the reactants; comparison with the oxidation with Ce(SO4)2*4H2O; Rate constantThermodynamic dataProduct distribution;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 56, # 10 p. 2412 - 2415,2132 - 2135
potassium hydroxide in water T=78°C; 0.333333 h; isomerization equilibrium; degradation to acids; varying time, OH(1-) concentration 0.001 M to O.1 M; also in presence of Ca(2+) up to 0.06 M; Rate constantProduct distributionMechanism;
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 106, # 2 p. 35 - 43
potassium hydroxide; Na2B2O7 in water T=78°C; 0.5 h; isomerization equilibrium; degradation to acids; varying time, borate molar ratio from 0.4 to 4.0; Rate constantProduct distributionMechanism;
参考文献
Bruijn, J. M. de; Kieboom, A. P. G.; Bekkum, H. van
Recueil des Travaux Chimiques des Pays-Bas, 1987 , vol. 106, # 2 p. 35 - 43
potassium hydroxide in water T=78°C; 0.333333 h; isomerization equilibrium; degradation to acids; varying time, OH(1-) concentration 0.001 M to O.1 M; also in presence of Ca(2+) up to 0.06 M; Rate constantProduct distributionMechanism;
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 106, # 2 p. 35 - 43
